When a piece of solid phosphorus is added to a flask containing chlorine gas, heat is evolved?

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27-01-2018
Chemistry

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When a piece of solid phosphorus is added to a flask containing chlorine gas, heat is evolved?

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jamuuj jamuuj · Answer 1 · 2018-02-06T09:46:46+01:00

jamuuj jamuuj

06-02-2018

White phosphorus burns spontaneously in chlorine to produce a mixture of two chlorides, phosphorus (ii) chloride and phosphorus(v) chloride and heat is evolved. Phosphorus (iii) chloride is a colorless fuming liquid:
P4 + 6Cl2 = 4PCl3
Phosphorus (v) chloride is an off-white solid
P4 +10Cl2 = 4PCl5

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